Cooperative role of halogen and hydrogen bonding in the stabilization of water adducts with apolar molecules

Author:

De Santis Matteo1234ORCID,Nunzi Francesca53412ORCID,Cesario Diego1234ORCID,Belpassi Leonardo53463ORCID,Tarantelli Francesco53412ORCID,Cappelletti David1234ORCID,Pirani Fernando1234ORCID

Affiliation:

1. Dipartimento di Chimica

2. Biologia e Biotecnologie

3. I-06123 Perugia

4. Italy

5. Istituto di Scienze e Tecnologie Molecolari del CNR (ISTM-CNR)

6. Consortium for Computational Molecular and Materials Sciences (CMS)2

Abstract

Conversely to the H2O–CF4 adduct, an appreciable intermolecular bond stabilization by charge transfer is operative in the H2O–CCl4 system.

Funder

Ministero dell'Istruzione, dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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