The dawn of hydrogen and halogen bonds and their crucial role in collisional processes probing long-range intermolecular interactions

Author:

Cappelletti David1ORCID,Falcinelli Stefano2ORCID,Pirani Fernando12ORCID

Affiliation:

1. Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, via Elce di Sotto 8, 06123 Perugia, Italy

2. Dipartimento di Ingegneria Civile ed Ambientale, Università degli Studi di Perugia, via G. Duranti 93, 06215 Perugia, Italy

Abstract

Concerted glory scattering experiments and quantum mechanical calculations allow to detect the emergence of hydrogen bonding (HB) and halogen bonding (XB) at long intermolecular distances; the case of Cl2–H2O is shown where both HB and XB are operative.

Publisher

Royal Society of Chemistry (RSC)

Reference114 articles.

1. in Special issue “Long-Range Intermolecular Interactions in chemistry and Physics” , Chem. Phys. Lett. , ed. S. Falcinelli and D. Cappelletti , 2022

2. in Special issue “ Intermolecular forces: from atoms and molecules to nanostructures” , Molecules , ed. J. M. C. Marques , F. Prudente and F. Pirani , 2022

3. Halogen Bonding in Supramolecular Chemistry

4. Imaging the halogen bond in self-assembled halogenbenzenes on silver

5. “Noncovalent Interaction”: A Chemical Misnomer That Inhibits Proper Understanding of Hydrogen Bonding, Rotation Barriers, and Other Topics

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