Metal alkyls programmed to generate metal alkylidenes by α-H abstraction: prognosis from NMR chemical shift-Reference-Cited by-同舟云学术

Metal alkyls programmed to generate metal alkylidenes by α-H abstraction: prognosis from NMR chemical shift

Published:2018 Issue:7 Volume:9 Page:1912-1918
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gordon Christopher P.¹²³⁴^ORCID,Yamamoto Keishi¹²³⁴^ORCID,Searles Keith¹²³⁴^ORCID,Shirase Satoru¹²³⁴⁵^ORCID,Andersen Richard A.⁵⁶⁷⁸^ORCID,Eisenstein Odile⁹¹⁰¹¹¹²¹³^ORCID,Copéret Christophe¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Applied Biosciences

2. ETH Zürich

3. Zürich

4. Switzerland

5. Department of Chemistry

6. University of California

7. Berkeley

8. USA

9. Institut Charles Gerhardt

10. UMR 5253 CNRS-UM-ENSCM

11. Université de Montpellier

12. 34095 Montpellier

13. France

Abstract

Chemical shift analysis predicts the ease of alkylidene formation from bis-alkyl d⁰ complexes via α-H abstraction.

Funder

Canon Foundation for Scientific Research

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC05039A

Reference62 articles.

1. Dimethyltitanocene: From Millimole to Kilomole

2. Recent Advances in High Oxidation State Mo and W Imido Alkylidene Chemistry

3. Metathesis of Alkanes and Related Reactions

4. C−H Bond Activation and Organometallic Intermediates on Isolated Metal Centers on Oxide Surfaces

5. First isolable transition metal methylene complex and analogs. Characterization, mode of decomposition, and some simple reactions

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