13Ccarbene nuclear magnetic resonance chemical shift analysis confirms CeIVC double bonding in cerium(<scp>iv</scp>)–diphosphonioalkylidene complexes-Reference-Cited by-同舟云学术

¹³C_carbene nuclear magnetic resonance chemical shift analysis confirms Ce^IVC double bonding in cerium(iv)–diphosphonioalkylidene complexes

Published:2024 Issue:1 Volume:15 Page:238-249
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Baker Cameron F.¹^ORCID,Seed John A.¹^ORCID,Adams Ralph W.¹^ORCID,Lee Daniel²^ORCID,Liddle Stephen T.¹^ORCID

Affiliation:

1. Department of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK

2. Department of Chemical Engineering, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK

Abstract

A combined solid-state NMR and DFT computational shielding study confirms the presence of CeC double bonds in cerium–diphosphonioalkylidene complexes.

Funder

Engineering and Physical Sciences Research Council

European Research Council

University of Manchester

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC04449A

Reference88 articles.

1. Phosphorus-substituted carbene complexes: Chelates, pincers and spirocycles

2. Bis-phosphorus stabilised carbene complexes

3. Metal–ligand multiple bonding in uranium: structure and reactivity

4. Early metal bis(phosphorus-stabilised)carbene chemistry

5. Uranium carbene compounds

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