Bonding and Reactivity of d0 Transition Metal Imido Complexes Encoded in Their 15N NMR Signatures
Author:
Affiliation:
1. Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 2, CH-8093 Zürich, Switzerland
2. Department of Chemistry, University of Minnesota−Twin Cities, Minneapolis, Minnesota 55455, United States
Funder
Schweizerischer Nationalfonds zur F?rderung der Wissenschaftlichen Forschung
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.3c14723
Reference57 articles.
1. Reactivity of terminal imido complexes of group 4–6 metals: Stoichiometric and catalytic reactions involving cycloaddition with unsaturated organic molecules
2. Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity
3. Prospects and challenges for nitrogen-atom transfer catalysis
4. Group 5 Imides and Bis(imide)s as Selective Hydrogenation Catalysts
5. Activation of carbon–hydrogen bonds and dihydrogen by 1,2-CH-addition across metal–heteroatom bonds
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1. Origin of Reactivity Trends of an Elusive Metathesis Intermediate from NMR Chemical Shift Analysis of Surrogate Analogues;Journal of the American Chemical Society;2024-07-09
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