Protonation and electrochemical reduction of rhodium– and iridium–dinitrogen complexes in organic solution-Reference-Cited by-同舟云学术

Protonation and electrochemical reduction of rhodium– and iridium–dinitrogen complexes in organic solution

Published:2017 Issue:41 Volume:46 Page:14325-14330
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Connor Gannon P.¹²³⁴^ORCID,Lease Nicholas⁵⁶⁷⁸⁴,Casuras Andrea⁵⁶⁷⁸⁴,Goldman Alan S.⁵⁶⁷⁸⁴,Holland Patrick L.¹²³⁴^ORCID,Mayer James M.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Yale University

3. New Haven

4. USA

5. Department of Chemistry and Chemical Biology

6. Rutgers

7. The State University of New Jersey

8. New Brunswick

Abstract

In iridium– and rhodium–pincer systems that support both hydrides and dinitrogen complexes, protonation and one-electron reduction lead to dinitrogen loss.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03476H

Reference43 articles.

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3. Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center

4. Challenges in reduction of dinitrogen by proton and electron transfer

5. Evaluating the Thermodynamics of Electrocatalytic N2 Reduction in Acetonitrile

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