Reductive Elimination of H2 Activates Nitrogenase to Reduce the N≡N Triple Bond: Characterization of the E4(4H) Janus Intermediate in Wild-Type Enzyme-Reference-Cited by-同舟云学术

Reductive Elimination of H2 Activates Nitrogenase to Reduce the N≡N Triple Bond: Characterization of the E4(4H) Janus Intermediate in Wild-Type Enzyme

Published:2016-08-16 Issue:33 Volume:138 Page:10674-10683
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Lukoyanov Dmitriy¹,Khadka Nimesh²,Yang Zhi-Yong²,Dean Dennis R.³,Seefeldt Lance C.²,Hoffman Brian M.¹

Affiliation:

1. Departments of Chemistry and Molecular Biosciences, Northwestern University, Evanston, Illinois 60208, United States

2. Department of Chemistry and Biochemistry, Utah State University, Logan, Utah 84322, United States

3. Department of Biochemistry, Virginia Tech, Blacksburg, Virginia 24061, United States

Funder

Division of Molecular and Cellular Biosciences

Basic Energy Sciences

National Institute of General Medical Sciences

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.6b06362

Reference32 articles.

1. Mechanism of Molybdenum Nitrogenase

2. Duplication and extension of the Thorneley and Lowe kinetic model for Klebsiella pneumoniae nitrogenase catalysis using a mathematica software platform

3. A Nitrogen Pressure of 50 Atmospheres Does Not Prevent Evolution of Hydrogen by Nitrogenase

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