Ni(<scp>i</scp>)–TPA stabilization by hydrogen bond formation on the second coordination sphere: a DFT characterization-Reference-Cited by-同舟云学术

Ni(i)–TPA stabilization by hydrogen bond formation on the second coordination sphere: a DFT characterization

Published:2022 Issue:33 Volume:51 Page:12585-12595
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Posada-Pérez Sergio¹^ORCID,Escayola Silvia¹²^ORCID,Poater Jordi³⁴^ORCID,Solà Miquel¹^ORCID,Poater Albert¹^ORCID

Affiliation:

1. Institut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona, C/ Maria Aurèlia Capmany, 69, 17003 Girona, Catalonia, Spain

2. Donostia International Physics Center (DIPC), Donostia, Euskadi, Spain

3. Departament de Química Inorgànica i Orgànica & IQTCUB, Universitat de Barcelona, 08028 Barcelona, Spain

4. ICREA, 08010 Barcelona, Spain

Abstract

We have characterized the Ni(i)– and Ni(ii)–TPA complexes and analyzed the role of hydrogen bonding in the stability of Ni(i)–TPA complexes. Our results prove the important contribution of hydrogen bonding in the stability of TPA–Ni(i)–F complexes.

Funder

Ministerio de Ciencia e Innovación

Universitat de Girona

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01355J

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