Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenes
Author:
Affiliation:
1. Department of Chemistry
2. Massachusetts Institute of Technology
3. Cambridge
4. USA
Abstract
The syntheses and 1,2-addition reactivities of nontrigonal phosphazenes supported by trianionic tricoordinating chelates of the type L3PNdipp (3: L3 = N[CHC(tBu)O]23−; 4: L3 = N(o-NMeC6H4)23−; dipp = 2,6-diisopropylphenyl) are reported.
Funder
Division of Chemistry
National Institute of General Medical Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC00929E
Reference55 articles.
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3. Transition and Main Group Metals in Cyclic Phosphazanes and Phosphazenes
4. Phosphazenes as scaffolds for the construction of multi-site coordination ligands
5. Iminophosphorane–phosphines: Versatile ligands for homogeneous catalysis
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