Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines-Reference-Cited by-同舟云学术

Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines

Published:2024 Issue:55 Volume:60 Page:7073-7076
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hu Lei¹²,Chakraborty Sayandip¹,Tumanov Nikolay¹^ORCID,Wouters Johan¹,Robiette Raphaël²^ORCID,Berionni Guillaume¹^ORCID

Affiliation:

1. Université de Namur, Department of Chemistry, Namur Institute of Structured Matter (NISM), Rue de Bruxelles 61, Namur 5000, Belgium

2. Université Catholique de Louvain, Institute of Condensed Matter and Nanosciences, Place Louis Pasteur 1 box L4.01.02, Louvain-la-Neuve 1348, Belgium

Abstract

Structure–reactivity investigations and parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled to design frustrated Lewis pairs with unusual properties due to the cage-shaped triptycene scaffold.

Funder

Chinese Government Scholarship

Namur Institute of Structured Matter, University of Namur

Fonds De La Recherche Scientifique - FNRS

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01868K

Reference58 articles.

1. Über neue organische Phosphorverbindungen III. Phosphinmethylenderivate und Phosphinimine

2. Catalytic aza-Wittig Cyclizations for Heteroaromatic Synthesis

3. Organophosphorus-Catalysed Staudinger Reduction

4. Catalytic Staudinger/Aza-Wittig Sequence by in situ Phosphane Oxide Reduction

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