Affiliation:
1. Bioinspired Coordination Chemistry and Homogeneous Catalysis Group Institute of Chemistry School of Mathematics and Sciences Carl von Ossietzky University Oldenburg Carl-von-Ossietzky-Straße 9–11 26129 Oldenburg Germany
Abstract
AbstractNonclassical P(III) centers have attracted much attention in recent years. Incorporating a P(III) center in a rigid bicyclic platform offers a particularly attractive way to invoke significant geometric distortion of the phosphorus atom that may in turn induce unusual reactivity. Although still relatively scarcely explored, phosphorus centers enforced in a non‐C3 symmetry have gained significant traction lately. However, the current scaffolds are based on a relatively limited set of design principles and ligand platforms associated therewith. This work is focussed on the synthesis as well as versatile oxidation, addition and coordination chemistry of a geometrically distorted P(III) species featuring a synthetically modular, nonsymmetric trisamine platform derived from 2‐(methylamino)‐N‐(2‐(methylamino)phenyl)benzenesulfonamide.
Funder
Deutsche Forschungsgemeinschaft
Subject
General Chemistry,Catalysis,Organic Chemistry
Cited by
5 articles.
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