A novel octacyanido dicobalt(iii) building block for the construction of heterometallic compounds-Reference-Cited by-同舟云学术

A novel octacyanido dicobalt(iii) building block for the construction of heterometallic compounds

Published:2019 Issue:17 Volume:43 Page:6675-6682
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Alexandru Maria-Gabriela¹²³⁴⁵^ORCID,Marino Nadia⁶⁷⁸⁹^ORCID,Visinescu Diana¹⁰¹¹¹²¹³¹⁴^ORCID,De Munno Giovanni⁶⁷⁸⁹^ORCID,Andruh Marius¹⁵¹⁶¹⁷¹⁸¹⁴^ORCID,Bentama Abdeslem¹⁹²⁰²¹²²²³,Lloret Francesc²⁴²⁵²⁶²⁷^ORCID,Julve Miguel²⁴²⁵²⁶²⁷^ORCID

Affiliation:

1. Department of Inorganic Chemistry

2. Physical Chemistry and Electrochemistry

3. Faculty of Applied Chemistry and Materials Science

4. University Politehnica of Bucharest

5. 011061 Bucharest

6. Dipartimento di Chimica e Tecnologie Chimiche

7. Università della Calabria

8. 87036 Rende

9. Italy

10. Coordination and Supramolecular Chemistry Laboratory

11. “Ilie Murglescu” Institute of Physical Chemistry

12. Romanian Academy

13. Bucharest 060021

14. Romania

15. Inorganic Chemistry Laboratory

16. Faculty of Chemistry

17. University of Bucharest

18. Bucharest

19. Laboratoire de Chimie Organique Appliquée

20. Faculté des Sciences Techniques de Fès

21. Université Sidi Mohammed Ben Abdellah

22. Fès

23. Morocco

24. Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol)

25. Universitat de València

26. 46990 Paterna

27. Spain

Abstract

The first bimetallic 3d cyanido-bearing complex with 2,5-dpp as a bridge, (Ph₄P)₂[Co₂^III(μ-2,5-dpp)(CN)₈]·2H₂O, is obtained and used as a metalloligand with the [Mn(MAC)(H₂O)₂]²⁺ cation to build a {Co^IIIMn^II} heterobimetallic chain.