A rare isostructural series of 3d–4f cyanido-bridged heterometallic squares obtained by assembling [FeIII{HB(pz)3}(CN)3]− and LnIII ions: synthesis, X-ray structure and cryomagnetic study

Author:

Alexandru Maria-Gabriela1ORCID,Visinescu Diana2ORCID,Cula Beatrice3ORCID,Shova Sergiu4ORCID,Rabelo Renato5ORCID,Moliner Nicolás5ORCID,Lloret Francesc5ORCID,Cano Joan5ORCID,Julve Miguel5ORCID

Affiliation:

1. Department of Inorganic Chemistry, Physical Chemistry and Electrochemistry, Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest, 1-7 Gh. Polizu Street, 011061 Bucharest, Romania

2. Coordination and Supramolecular Chemistry Laboratory, “Ilie Murgulescu” Institute of Physical Chemistry, Romanian Academy, Splaiul Independentei 202, Bucharest 060021, Romania

3. Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489 Berlin, Germany

4. “Petru Poni” Institute of Macromolecular Chemistry, Ro, an Academy, mani, Aleea Grigore Ghica Vodă 41-A, RO-700487 Iasi, Romania

5. Departament de Química Inorgànica/Instituto de Ciencia Molecular, Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, València, Spain

Abstract

A rare isostructural series of cyanido-bridged {FeIIILnIII}2 square-shaped heterobimetallic complexes were obtained, in which TbIII, DyIII and ErIII derivatives show slow magnetization relaxation under zero and non-zero static fields.

Funder

Generalitat Valenciana

Ministerio de Economía y Competitividad

Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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