Cyanido-bridged {FeIIILnIII} heterobimetallic chains assembled through the [FeIII{HB(pz)3}(CN)3]− complex as metalloligand: synthesis, crystal structure and magnetic properties

Author:

Visinescu Diana12345ORCID,Alexandru Maria-Gabriela67895ORCID,Dumitrescu Dan G.101112ORCID,Shova Sergiu133145,Moliner Nicolás15161718ORCID,Lloret Francesc15161718ORCID,Julve Miguel15161718ORCID

Affiliation:

1. Coordination and Supramolecular Chemistry Laboratory

2. “Ilie Murgulescu” Institute of Physical Chemistry

3. Romanian Academy

4. Bucharest 060021

5. Romania

6. Department of Inorganic Chemistry, Physical Chemistry and Electrochemistry

7. Faculty of Applied Chemistry and Materials Science

8. University Politehnica of Bucharest

9. 011061 Bucharest

10. Elettra Sincrotrone Trieste SCpA

11. Basovizza

12. Italy

13. “Petru Poni” Institute of Macromolecular Chemistry

14. RO-700487 Iasi

15. Departament de Química Inorgànica/Instituto de Ciencia Molecular

16. Universitat de València

17. 46980 Paterna

18. Spain

Abstract

The first isostructural series of cyanido-bridged 3d–4f chains showing a unique zig-zag motif have been obtained by using the heteroleptic [FeIII{HB(pz)3}(CN)3] complex as a metalloligand towards the preformed [LnIII(bpdo)(NO3)2(H2O)]+ species.

Funder

Unitatea Executiva pentru Finantarea Invatamantului Superior, a Cercetarii, Dezvoltarii si Inovarii

Generalitat Valenciana

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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