Rate coefficient of the reaction CH2OO + NO2 probed with a quantum-cascade laser near 11 μm-Reference-Cited by-同舟云学术

Rate coefficient of the reaction CH2OO + NO2 probed with a quantum-cascade laser near 11 μm

Published:2019 Issue:32 Volume:21 Page:17578-17583
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Luo Pei-Ling¹²³^ORCID,Chung Chen-An⁴⁵³,Lee Yuan-Pern¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Atomic and Molecular Sciences Academia Sinica

2. Taipei 10617

3. Taiwan

4. Department of Applied Chemistry and Institute of Molecular Science National Chiao Tung University

5. Hsinchu 30010

Abstract

Employing a cw quantum-cascade laser coupled with Herriott mirrors to probe CH₂OO, we report a rate coefficient k = (1.0 ± 0.2) × 10⁻¹² cm³ molecule⁻¹ s⁻¹ for the reaction CH₂OO + NO₂ at 298 K, which is much smaller than literature values.

Funder

Ministry of Science and Technology, Taiwan

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP03333E

Reference39 articles.

1. The gas-phase ozonolysis of unsaturated volatile organic compounds in the troposphere

2. J. G. Calvert , R.Atkinson , J. A.Kerr , S.Madronich , G. K.Moortgat , T. J.Wallington and G.Yarwood , The Mechanisms of Atmospheric Oxidation of the Alkenes , Oxford University Press , Oxford , 2000

3. Gas-Phase Ozonolysis of Alkenes. Recent Advances in Mechanistic Investigations

4. Die Ozonisierung des 9,10-Oktalins

5. Direct Kinetic Measurements of Criegee Intermediate (CH 2 OO) Formed by Reaction of CH 2 I with O 2

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