The titanium tris-anilide cation [Ti(N[tBu]Ar)3]+ stabilized as its perfluoro-tetra-phenylborate salt: structural characterization and synthesis in connection with redox activity of 4,4′-bipyridine dititanium complexes-Reference-Cited by-同舟云学术

The titanium tris-anilide cation [Ti(N[tBu]Ar)3]+ stabilized as its perfluoro-tetra-phenylborate salt: structural characterization and synthesis in connection with redox activity of 4,4′-bipyridine dititanium complexes

Published:2015 Issue:15 Volume:44 Page:6784-6796
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Spinney Heather A.¹²³⁴,Clough Christopher R.¹²³⁴,Cummins Christopher C.¹²³⁴

Affiliation:

1. 6-435 Department of Chemistry

2. Massachusetts Institute of Technology

3. Cambridge

4. USA

Abstract

A rare cationic d⁰ metal tris-amide complex, containing an intriguing pyramidal TiN₃ core geometry, namely {Ti(N[^tBu]Ar)₃}⁺, is isolated as its [B(C₆F₅)₄]⁻ salt.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00105F

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4. Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents

5. Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI2, the Kagan Reagent

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