Dihydrogen cleavage by a dimetalloxycarbene–borane frustrated Lewis pair-Reference-Cited by-同舟云学术

Dihydrogen cleavage by a dimetalloxycarbene–borane frustrated Lewis pair

Published:2021 Issue:31 Volume:50 Page:10692-10695
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Paparo Albert¹²³⁴^ORCID,Nguyen Anh L. P.⁵⁶⁷⁸^ORCID,Silvia Jared S.⁹¹⁰¹¹¹²,Spaniol Thomas P.¹²³⁴,Maron Laurent¹³¹⁴¹⁵¹⁶¹⁷^ORCID,Cummins Christopher C.⁹¹⁰¹¹¹²^ORCID,Okuda Jun¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. RWTH Aachen University

3. 52056 Aachen

4. Germany

5. School of Chemistry

6. Monash University

7. Clayton

8. Australia

9. Department of Chemistry

10. Massachusetts Institute of Technology

11. Cambridge

12. USA

13. Université de Toulouse et CNRS

14. INSA

15. UPS

16. UMR 5215

17. F-31077 Toulouse

Abstract

Dititanoxycarbene [(TiX₃)₂(μ-CO₂)] (X = N[^tBu](3,5-Me₂C₆H₃)) and B(C₆F₅)₃ cleaved dihydrogen under ambient conditions to give the zwitterionic formate [(TiX₃)₂(μ-OCHO-κO:κO′)(B(C₆F₅)₃)] and the hydrido borate [Ti(N[^tBu]Ar)₃][HB(C₆F₅)₃].

Funder

Deutsche Forschungsgemeinschaft

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02273C

Reference32 articles.

1. Reversible, Metal-Free Hydrogen Activation

2. Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes

3. Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

4. Frustrated Lewis Pair Chemistry: Development and Perspectives

5. Frustrated Lewis Pairs: From Concept to Catalysis

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