Nickel coordination chemistry of bis(dithiocarbazate) Schiff base ligands; metal and ligand centred redox reactions
Author:
Affiliation:
1. School of Chemistry and Molecular Biosciences
2. University of Queensland
3. Brisbane
4. Australia
Abstract
The tetradentate N2S2 Schiff base ligands derived from condensing S-methyl or S-benzyl dithiocarbazate with acetylacetone have been found to be versatile chelators for nickel and undergo a variety of ligand centred oxidations.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03204B
Reference23 articles.
1. Formation and Reactivity of Copper Acetylacetone Bis(Thiosemicarbazone) Complexes
2. Isomerism and reactivity of nickel(ii) acetylacetonate bis(thiosemicarbazone) complexes
3. Coordination chemistry of S-substituted isothiosemicarbazides and isothiosemicarbazones
4. Hidden Noninnocence: Theoretical and Experimental Evidence for Redox Activity of a β-Diketiminate(1−) Ligand
5. Trivalent copper stabilised by acetylacetone dithiocarbazate Schiff base ligands: structural, spectroscopic and electrochemical properties
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