Isomerism and reactivity of nickel(ii) acetylacetonate bis(thiosemicarbazone) complexes-Reference-Cited by-同舟云学术

Isomerism and reactivity of nickel(ii) acetylacetonate bis(thiosemicarbazone) complexes

Published:2018 Issue:6 Volume:47 Page:2018-2030
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bilyj Jessica K.¹²³⁴,Riley Mark J.¹²³⁴^ORCID,Bernhardt Paul V.¹²³⁴^ORCID

Affiliation:

1. School of Chemistry and Molecular Biosciences

2. University of Queensland

3. Brisbane

4. Australia

Abstract

The formation of asymmetric and symmetric nickel(ii) bis-thiosemicarbazone complexes has been investigated by NMR and UV-Vis spectroscopy which shed new light on the complexation mechanism and reactivity of these unusual isomers.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04337F

Reference35 articles.

1. Thiosemicarbazones from the Old to New: Iron Chelators That Are More Than Just Ribonucleotide Reductase Inhibitors

2. New Iminodiacetate–Thiosemicarbazone Hybrids and Their Copper(II) Complexes Are Potential Ribonucleotide Reductase R2 Inhibitors with High Antiproliferative Activity

3. Thiosemicarbazone complexes of copper(II): structural and biological studies

4. Studies on the Mechanism of Hypoxic Selectivity in Copper Bis(Thiosemicarbazone) Radiopharmaceuticals

5. CuII(atsm) improves the neurological phenotype and survival of SOD1G93A mice and selectively increases enzymatically active SOD1 in the spinal cord

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