Nickel(ii) complexes with 14-membered bis-thiosemicarbazide and bis-isothiosemicarbazide ligands: synthesis, characterization and catalysis of oxygen evolution reaction

Author:

Besleaga Iuliana1ORCID,Fesenko Anastasia A.2,Paul Anup3ORCID,Šljukić Biljana4ORCID,Rapta Peter5,Pombeiro Armando J. L.3ORCID,Shutalev Anatoly D.6ORCID,Arion Vladimir B.17ORCID

Affiliation:

1. University of Vienna, Institute of Inorganic Chemistry, Währinger Strasse 42, A-1090 Vienna, Austria

2. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky Ave., 119071 Moscow, Russian Federation

3. Centro de Química Estrutural, Institute of Molecular Sciences, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

4. Center of Physics and Engineering of Advanced Materials, Laboratory of Physics of Materials and Emerging Technologies, Chemical Engineering Department, Instituto Superior Técnico, Universidade de Lisboa, 1049-001, Lisbon, Portugal

5. Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Radlinského 9, SK-81237 Bratislava, Slovak Republic

6. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., 119991 Moscow, Russian Federation

7. Inorganic Polymers Department, “Petru Poni” Institute of Macromolecular Chemistry, Aleea Gr. Ghica Voda 41 A, Iasi 700487, Romania

Abstract

The Ni(ii) complexes reported in this work show high performance for OER and are suggested as promising candidates for alkaline water electrolysis.

Funder

Russian Science Foundation

Fundação para a Ciência e a Tecnologia

Agentúra na Podporu Výskumu a Vývoja

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

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