Catalytic asymmetric addition to cyclic <i>N</i>-acyl-iminium: access to sulfone-bearing contiguous quaternary stereocenters-Reference-Cited by-同舟云学术

Catalytic asymmetric addition to cyclic N-acyl-iminium: access to sulfone-bearing contiguous quaternary stereocenters

Published:2022 Issue:71 Volume:58 Page:9942-9945
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bhosale Viraj A.¹,Císařová Ivana²,Kamlar Martin¹,Veselý Jan¹^ORCID

Affiliation:

1. Department of Organic Chemistry, Faculty of Science, Charles University, 128 43 Prague, Czech Republic

2. Department of Inorganic Chemistry, Faculty of Science, Charles University, 128 43 Prague, Czech Republic

Abstract

Herein, we report the first chiral phosphoric acid (CPA)-catalyzed asymmetric addition of α-fluoro(phenylsulfonyl)methane (FSM) derivatives to in situ generated cyclic N-acyliminium.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02667H

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