Mono- and binuclear chiral N,N,O-scorpionate zinc alkyls as efficient initiators for the ROP of rac-lactide-Reference-Cited by-同舟云学术

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Mono- and binuclear chiral N,N,O-scorpionate zinc alkyls as efficient initiators for the ROP of rac-lactide

Published:2017 Issue:43 Volume:46 Page:15107-15117
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Otero Antonio¹²³⁴⁵^ORCID,Fernández-Baeza Juan¹²³⁴⁵^ORCID,Sánchez-Barba Luis F.⁶⁷⁸⁹¹⁰^ORCID,Sobrino Sonia¹²³⁴⁵^ORCID,Garcés Andrés⁶⁷⁸⁹¹⁰^ORCID,Lara-Sánchez Agustín¹²³⁴⁵^ORCID,Rodríguez Ana M.¹²³⁴⁵^ORCID

Affiliation:

1. Universidad de Castilla-La Mancha

2. Departamento de Química Inorgánica

3. Orgánica y Bioquímica

4. Centro de Innovación en Química Avanzada (ORFEO-CINQA) Campus Universitario

5. 13071-Ciudad Real

6. Universidad Rey Juan Carlos

7. Departamento de Biología y Geología

8. Física y Química Inorgánica

9. Móstoles-28933

10. Spain

Abstract

Activity enhancement in the ROP ofrac-LA through the cooperative effect of two remote zinc metals in N,N,O-scorpionate binuclear trisalkyls.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03045B

Reference65 articles.

1. Stereocontrolled ring-opening polymerisation of lactide

2. Lactide Synthesis and Chirality Control for Polylactic acid Production

3. Synthetic Polymers from Sugar-Based Monomers

4. Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters

5. Aliphatic polyester polymer stars: synthesis, properties and applications in biomedicine and nanotechnology

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2. Exploring enantiopure zinc-scorpionates as catalysts for the preparation of polylactides, cyclic carbonates, and polycarbonates;Dalton Transactions;2024

3. Zinc Complexes Bearing Dinucleating Bis(imino‐ pyridine)binaphthol Ligands: Highly Active and Robust Catalysts for the Lactide Polymerization;ChemCatChem;2023-06-06

4. A Multitool for Circular Economy: Fast Ring‐Opening Polymerization and Chemical Recycling of (Bio)polyesters Using a Single Aliphatic Guanidine Carboxy Zinc Catalyst;ChemSusChem;2023-06

5. N-alkyl-β-ketoiminate zinc complexes: Synthesis, structure, and reactivity in ring-opening polymerization of lactide;Inorganica Chimica Acta;2023-01

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