Exploring enantiopure zinc-scorpionates as catalysts for the preparation of polylactides, cyclic carbonates, and polycarbonates-Reference-Cited by-同舟云学术

Exploring enantiopure zinc-scorpionates as catalysts for the preparation of polylactides, cyclic carbonates, and polycarbonates

Published:2024 Issue:33 Volume:53 Page:13933-13949
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Navarro Marta¹²^ORCID,Sobrino Sonia¹,Fernández Israel³^ORCID,Lara-Sánchez Agustín¹^ORCID,Garcés Andrés²^ORCID,Sánchez-Barba Luis F.²^ORCID

Affiliation:

1. Universidad de Castilla-La Mancha, Departamento de Química Inorgánica, Orgánica y Bioquímica-Centro de Innovación en Química Avanzada (ORFEO-CINQA), Campus Universitario, 13071-Ciudad Real, Spain

2. Universidad Rey Juan Carlos, Departamento de Biología y Geología, Física y Química Inorgánica, Móstoles-28933-Madrid, Spain

3. Universidad Complutense de Madrid. Departamento de Química Orgánica I and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias Químicas, 28040, Madrid, Spain

Abstract

Novel enantiopure zinc scorpionates as very efficient and versatile catalysts for sustainable processes such as the production of iso-enriched poly(rac-lactide) (Pi = 0.88), five-membered cyclic carbonates and poly(cyclohexene carbonate)s.

Funder

Junta de Comunidades de Castilla-La Mancha

Universidad de Castilla-La Mancha

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01526F

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3. Syntheses and crystal structures of lithium and niobium complexes containing a new type of monoanionic “scorpionate” ligand †

4. One-pot terpolymerization of CHO, CO₂andl-lactide using chloride indium catalysts