η6-Coordinated ruthenabenzenes from three-component assembly on a diruthenium μ-allenyl scaffold

Author:

Bresciani Giulio12,Zacchini Stefano32ORCID,Pampaloni Guido12ORCID,Bortoluzzi Marco42ORCID,Marchetti Fabio12ORCID

Affiliation:

1. University of Pisa, Department of Chemistry and Industrial Chemistry, Via G. Moruzzi 13, I-56124 Pisa, Italy

2. CIRCC, Via Celso Ulpiani 27, I-70126 Bari, Italy

3. University of Bologna, Department of Industrial Chemistry “Toso Montanari”, Viale Risorgimento 4, I-40136 Bologna, Italy

4. University of Venezia “Ca’ Foscari”, Department of Molecular Science and Nanosystems, Via Torino 155, I-30170 Mestre (VE), Italy

Abstract

A series of three ruthenabenzenes acting as hetero-arene ligands towards a second Ru centre was synthesized from a dimetallic precursor via double C–C bond coupling between allenyl, carbon monoxide and alkyne units.

Funder

Università di Pisa

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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