Skeletal Rearrangement of a μ–η2:η4-Hexatrienyl Ligand at a Diruthenium Site via a μ–η5-Ruthenacyclohexadienyl Intermediate
Author:
Affiliation:
1. Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan
Funder
Japan Society for the Promotion of Science
Publisher
American Chemical Society (ACS)
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.4c00050
Reference50 articles.
1. Alkyne Scission on Metal Cluster Frameworks
2. Reactions of alkynes with bridging alkylidyne ligands in metal complexes: X-ray crystal structures of [FeW{µ2-C(C6H4Me-4)·C(Me)·C(Me)}(CO)5(η-C5H5)] and [Fe2W(µ3-CC6H4Me-4)(µ2-Me3SiC2SiMe3)(µ-CO)(CO)6(η-C5H5)]
3. An unprecedented bis(carbyne) cluster rearrangement involving simultaneous coupling and decoupling of carbyne fragments: a new homogeneous model for carbon-carbon bond forming and bond breaking on surfaces
4. Molecular structure and dynamic solution behavior of the bridging 1,3-dimetallaallyl ligand in (Me3SiCH2)4W2(.mu.-CSiMe3)(.mu.-C3R2SiMe3) compounds (R = hydrogen, methyl, or phenyl) formed by insertion of alkynes into a bridging (.mu.2) ligand
5. Reaction of polynuclear acetylide clusters. Mixed-metal complexes derived from reactions of CpWOs3(CO)11(C.tplbond.CR) (R = Ph, nBu) with disubstituted alkynes
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