Inherent and transferable stabilization energies of carbon- and heteroatom-centred radicals on the same relative scale and their applications
Author:
Affiliation:
1. Research School of Chemistry
2. Australian National University
3. Canberra, Australia
4. Department of Chemistry and Biochemistry
5. Long Island University
6. Brooklyn, USA
Abstract
A predictive scheme for ranking the inherent stabilities of carbon- and heteroatom-centred radicals on the same relative scale is presented.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP00537F
Reference40 articles.
1. Organic Compound Synthesis on the Primitive Earth
2. Persistent carbon-centered radicals
3. S. W. Benson , Thermochemical Kinetics. Methods for the Estimation of Thermochemical Data and Rate Parameters , John Wiley & Sons , New York , 1976
4. Stabilization energies and structures of substituted methyl radicals
5. CH bond dissociation energies, isolated stretching frequencies, and radical stabilization energy
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