Experimental and theoretical study of the mechanism and rate constants of the sequential 5-<i>exo-trig</i> spirocyclization involving vinyl, aryl and <i>N</i>-alkoxyaminyl radicals-Reference-Cited by-同舟云学术

Experimental and theoretical study of the mechanism and rate constants of the sequential 5-exo-trig spirocyclization involving vinyl, aryl and N-alkoxyaminyl radicals

Published:2022 Issue:20 Volume:20 Page:4141-4154
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Bejarano Carlos A.¹²^ORCID,Díaz John E.¹^ORCID,Cifuentes-López Andrés³^ORCID,López Lina V.¹^ORCID,Jaramillo-Gómez Luz M.⁴^ORCID,Buendia-Atencio Cristian²^ORCID,Lorett Velásquez Vaneza Paola⁵^ORCID,Mejía Sol M.¹^ORCID,Loaiza Alix E.¹^ORCID

Affiliation:

1. Departamento de Química, Facultad de Ciencias, Pontificia Universidad Javeriana, Bogotá 11001000, Colombia

2. Departamento de Química, Facultad de Ciencias, Universidad Antonio Nariño, Bogotá 110231, Colombia

3. Department of Chemistry, Rutgers University, Newark, NJ 07102, USA

4. Departamento de Química, Facultad de Ciencias, Universidad del Valle, Cali 760032, Colombia

5. Facultad de Medicina y Ciencias de la Salud, Universidad Militar Nueva Granada, Bogotá, Colombia

Abstract

The mechanism and kinetic constants of the cascade cyclization involving vinyl, aryl and N-alkoxyaminyl radicals for the formation of 1-azaspiro[4.4]nonanes.

Funder

Pontificia Universidad Javeriana

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB00387B

Reference61 articles.

1. J.Pérard-Viret , L.Quteishat , R.Alsalim , J.Royer and F.Dumas , in The Alkaloids , ed. H.-J. Knölker , Academic Press , 2017 , vol. 78 , ch. 4

2. Conformationally Constrained Nicotines: Polycyclic, Bridged, and Spiro-Annulated Analogues as Novel Ligands for the Nicotinic Acetylcholine Receptor

3. Structural classification and biological activities of Stemona alkaloids

4. Kinetics and mechanism of some vinyl radical cyclisations

5. Regio- and stereo-selectivity of alkenyl radical ring closure: A theoretical study

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Study of the Mechanism of 7‐exo‐trig Cyclizations of Aryl, Vinyl, and Alkyl Radicals on Oxime Ethers;European Journal of Organic Chemistry;2024-01-19