Structural and magnetic properties of some lanthanide (Ln = Eu(iii), Gd(iii) and Nd(iii)) cyanoacetate polymers: field-induced slow magnetic relaxation in the Gd and Nd substitutions-Reference-Cited by-同舟云学术

Structural and magnetic properties of some lanthanide (Ln = Eu(iii), Gd(iii) and Nd(iii)) cyanoacetate polymers: field-induced slow magnetic relaxation in the Gd and Nd substitutions

Published:2014 Issue:32 Volume:43 Page:12342-12356
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Arauzo A.¹²³⁴²,Lazarescu A.⁵⁶⁷,Shova S.⁵⁶⁷⁸⁹,Bartolomé E.¹⁰¹¹,Cases R.³⁴²,Luzón J.³⁴²¹²¹³,Bartolomé J.³⁴²,Turta C.⁵⁶⁷

Affiliation:

1. Servicio de Medidas Físicas. Universidad de Zaragoza

2. 50009 Zaragoza, Spain

3. Instituto de Ciencia de Materiales de Aragón

4. CSIC-Universidad de Zaragoza

5. Institute of Chemistry

6. Academy of Sciences of Moldova

7. MD-2028, Chisinau, Moldova

8. “Petru Poni” Institute of Macromolecular Chemistry

9. 700487 Iasi, Romania

10. Escola Universitària Salesiana de Sarrià (EUSS)

11. 08017-Barcelona, Spain

12. Centro Universitario de la Defensa. Academia General Militar

13. Zaragoza, Spain

Abstract

The cyanoacetate complexes, {[Ln₂(CNCH₂COO)₆(H₂O)₄]·2H₂O}_n, with Ln = Gd, Nd, show field-induced slow relaxation: resonant phonon trapping and Orbach process for Gd, and Orbach and direct processes for Nd.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01104J

Reference76 articles.

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4. Lanthanide complexes with 8-quinolinyloxyacetate (qoa): Synthesis and supramolecular assembly by hydrogen bonds

5. Crystal structures and luminescent properties of the lanthanide picrate complexes with an amide-type tripodal ligand

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