From field-induced to zero-field SMMs associated with open/closed structures of bis(ZnDy) tetranuclear complexes: a combined magnetic, theoretical and optical study

Author:

Zabala-Lekuona Andoni1ORCID,Lopez de Pariza Xabier2ORCID,Díaz-Ortega Ismael F.34ORCID,Cepeda Javier1ORCID,Nojiri Hiroyuki4ORCID,Gritsan Nina P.5ORCID,Dmitriev Alexey A.5ORCID,López-Ortega Alberto678ORCID,Rodríguez-Diéguez Antonio9ORCID,Seco José M.1ORCID,Colacio Enrique9ORCID

Affiliation:

1. Departamento de Química Aplicada, Facultad de Química, Universidad del País Vasco (UPV/EHU), 20018 Donostia-San Sebastián, Spain

2. POLYMAT and Department of Polymers and Advanced Materials: Physics, Chemistry and Technology, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel de Lardizabal 3, Donostia-San Sebastián 20018, Spain

3. Departamento de Química y Física-CIESOL, Universidad de Almería, Ctra. Sacramento s/n, 04120 Almería, Spain

4. Institute for Materials Research, Tohoku University, Katahira, Sendai, 980-8577, Japan

5. Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk, Russia

6. Departamento de Ciencias, Universidad Pública de Navarra, E-31006 Pamplona, Spain

7. Institute for Advanced Materials and Mathematics (INAMAT2), Universidad Pública de Navarra, E-31006 Pamplona, Spain

8. CIC nanoGUNE BRTA, Tolosa Hiribidea 76, Donostia-San Sebastian, 20018, Spain

9. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, 18071 Granada, Spain

Abstract

Introducing a dicarboxylate linker in a linear tetranuclear bis(ZnDy) complex enables the serendipitous formation of a cyclic version of the system with a Ueff = 342 K.

Funder

Junta de Andalucía

Universidad Pública de Navarra

Diputación Foral de Gipuzkoa

Russian Science Foundation

Ministerio de Ciencia e Innovación

Institute for Materials Research, Tohoku University

Eusko Jaurlaritza

Agencia Estatal de Investigación

Euskal Herriko Unibertsitatea

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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