Luminescence, chiroptical, magnetic and ab initio crystal-field characterizations of an enantiopure helicoidal Yb(iii) complex-Reference-Cited by-同舟云学术

Luminescence, chiroptical, magnetic and ab initio crystal-field characterizations of an enantiopure helicoidal Yb(iii) complex

Published:2021 Issue:4 Volume:8 Page:914-926
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Gendron Frédéric¹²³⁴⁵^ORCID,Di Pietro Sebastiano⁶⁷⁸⁹¹⁰^ORCID,Abad Galán Laura⁶⁷⁸⁹¹⁰^ORCID,Riobé François⁶⁷⁸⁹¹⁰^ORCID,Placide Virginie⁶⁷⁸⁹¹⁰,Guy Laure⁶⁷⁸⁹¹⁰^ORCID,Zinna Francesco¹¹¹²¹³¹⁴^ORCID,Di Bari Lorenzo¹¹¹²¹³¹⁴^ORCID,Bensalah-Ledoux Amina⁶¹⁵¹⁶¹⁷⁵^ORCID,Guyot Yannick⁶¹⁵¹⁶¹⁷⁵^ORCID,Pilet Guillaume⁶¹⁸¹⁹¹⁷⁵^ORCID,Pointillart Fabrice¹²³⁴⁵^ORCID,Baguenard Bruno⁶¹⁵¹⁶¹⁷⁵,Guy Stephan⁶¹⁵¹⁶¹⁷⁵^ORCID,Cador Olivier¹²³⁴⁵^ORCID,Maury Olivier⁶⁷⁸⁹¹⁰^ORCID,Le Guennic Boris¹²³⁴⁵^ORCID

Affiliation:

1. Univ. Rennes

2. CNRS

3. ISCR (Institut des Sciences Chimiques de Rennes) - UMR 6226

4. F-35000 Rennes

5. France

6. Univ. Lyon

7. ENS de Lyon

8. CNRS Laboratoire de Chimie UMR 5182

9. Université Claude Bernard Lyon 1

10. F-69342 Lyon

11. Dipartimento di Chimica e Chimica Industriale

12. Università di Pisa

13. 56124 Pisa

14. Italy

15. Institut Lumière Matière

16. UMR 5306 CNRS–Université Claude Bernard Lyon 1

17. 69622 Villeurbanne Cedex

18. Laboratoire des Multimatériaux et Interfaces (LMI)

19. UMR 5615 CNRS-Université Claude Bernard Lyon 1

Abstract

The electronic structure of a chiral Yb(iii)-based complex is fully determined by taking advantage of experimental magnetic, luminescence, and chiroptical (NIR-ECD and CPL) characterizations in combination with ab initio wavefunction calculations.

Funder

Agence Nationale de la Recherche

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QI/D0QI01194K

Reference87 articles.

1. Exploiting single-ion anisotropy in the design of f-element single-molecule magnets

2. Lanthanide Single-Molecule Magnets