Covalency versus magnetic axiality in Nd molecular magnets: Nd-photoluminescence, strong ligand-field, and unprecedented nephelauxetic effect in fullerenes NdM2N@C80 (M = Sc, Lu, Y)-Reference-Cited by-同舟云学术

Covalency versus magnetic axiality in Nd molecular magnets: Nd-photoluminescence, strong ligand-field, and unprecedented nephelauxetic effect in fullerenes NdM₂N@C₈₀ (M = Sc, Lu, Y)

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yang Wei¹,Rosenkranz Marco¹,Velkos Georgios¹,Ziegs Frank¹,Dubrovin Vasilii¹^ORCID,Schiemenz Sandra¹,Spree Lukas¹²^ORCID,de Souza Barbosa Matheus Felipe¹,Guillemard Charles³^ORCID,Valvidares Manuel³,Büchner Bernd¹,Liu Fupin¹^ORCID,Avdoshenko Stanislav M.¹,Popov Alexey A.¹^ORCID

Affiliation:

1. Leibniz Institute for Solid State and Materials Research (IFW Dresden), 01069 Dresden, Germany

2. Center for Quantum Nanoscience, Institute for Basic Science (IBS), Seoul, Republic of Korea

3. ALBA Synchrotron Light Source, E-08290 Barcelona, Spain

Abstract

Nd-luminescence in NdM2N@C80 (M = Sc, Lu, Y) reveals the relationship between strain, ligand-field splitting, nephelauxetic effect, and magnetic axiality.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05146C

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