The hidden features of fullerene rotation in the crystal lattice

Author:

Hao Yajuan12,Wang Yaofeng1,Feiler Christian G.3,Weiss Manfred S.3ORCID,Popov Alexey A.1ORCID,Liu Fupin4ORCID

Affiliation:

1. Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstr. 20, 01069, Dresden, Germany

2. School of Electrical and Mechanical Engineering, Pingdingshan University, Pingdingshan 467000, China

3. Macromolecular Crystallography (BESSY-MX), Elektronenspeicherring BESSY II, Helmholtz Zentrum Berlin, Albert-Einstein-Str. 15, 12489 Berlin, Germany

4. Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China

Abstract

Variable-temperature single-crystal X-ray diffraction elaborated the phase transition in Sc3N@C70 crystals and allowed to distinguish hidden static disorder from dynamic disorder caused by thermal motion.

Funder

Deutsche Forschungsgemeinschaft

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

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