Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediates-Reference-Cited by-同舟云学术

Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediates

Published:2015 Issue:7 Volume:6 Page:3706-3711
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yatham Veera Reddy¹²³⁴,Neudörfl Jörg-M.¹²³⁴,Schlörer Nils E.¹²³⁴,Berkessel Albrecht¹²³⁴

Affiliation:

1. Department of Chemistry

2. Cologne University

3. 50939 Cologne

4. Germany

Abstract

NMR/X-ray evidence is provided for hitherto postulated reactivity patterns of homoenolate vs. azolium enolate intermediates in NHC-catalyzed umpolung of enals.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01027F

Reference50 articles.

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2. Durch N-heterocyclische Carbene katalysierte Dominoreaktionen

3. Organocatalytic umpolung: N-heterocyclic carbenes and beyond

4. P.-C. Chiang and J. W.Bode, Science of Synthesis: Asymmetric Organocatalysis, ed. B. List, Thieme, Stuttgart, 2012, vol. 1, pp. 639–672

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