Formation of Breslow Intermediates from N‐Heterocyclic Carbenes and Aldehydes Involves Autocatalysis by the Breslow Intermediate, and a Hemiacetal-Reference-Cited by-同舟云学术

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Formation of Breslow Intermediates from N‐Heterocyclic Carbenes and Aldehydes Involves Autocatalysis by the Breslow Intermediate, and a Hemiacetal

Published:2022-05-02 Issue:23 Volume:61 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Wessels Alina¹^ORCID,Klussmann Martin²³^ORCID,Breugst Martin¹^ORCID,Schlörer Nils E.¹^ORCID,Berkessel Albrecht¹^ORCID

Affiliation:

1. Department of Chemistry Organic Chemistry University of Cologne Greinstraße 4 50939 Cologne Germany

2. Max-Planck-Institut für Kohlenforschung Kaiser-Wilhelm-Platz 1 45470 Mülheim an der Ruhr Germany

3. Borchers GmbH Berghausener Straße 100 40764 Langenfeld Germany

Funder

Deutsche Forschungsgemeinschaft

Universität zu Köln

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202117682

Reference83 articles.

1. RAPID DEUTERIUM EXCHANGE IN THIAZOLIUM SALTS1

2. On the Mechanism of Thiamine Action. IV.1 Evidence from Studies on Model Systems

3.

4. Tale of the Breslow intermediate, a central player in N-heterocyclic carbene organocatalysis: then and now

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