On the Mechanism of N-Heterocyclic Carbene-Catalyzed Reactions Involving Acyl Azoliums
Author:
Affiliation:
1. Laboratorium für Organische Chemie, ETH−Zürich, Wolfgang Pauli Strasse 10, 8093 Zürich, Switzerland
Publisher
American Chemical Society (ACS)
Subject
General Medicine,General Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ar400239v
Reference97 articles.
1. Organocatalytic umpolung: N-heterocyclic carbenes and beyond
2. NHCs in Asymmetric Organocatalysis: Recent Advances in Azolium Enolate Generation and Reactivity
3. Exploiting Acyl and Enol Azolium Intermediates via N-Hetero- cyclic Carbene-Catalyzed Reactions of α-Reducible Aldehydes
4. Origin of the β-Lactam Carbons in Clavulanic Acid from an Unusual Thiamine Pyrophosphate-Mediated Reaction
5. Observation of an Acryloyl−Thiamin Diphosphate Adduct in the First Step of Clavulanic Acid Biosynthesis
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