Linking Cr3 triangles through phosphonates and lanthanides: synthetic, structural, magnetic and EPR studies-Reference-Cited by-同舟云学术

Linking Cr3 triangles through phosphonates and lanthanides: synthetic, structural, magnetic and EPR studies

Published:2014 Issue:35 Volume:43 Page:13242-13249
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Zangana Karzan H.¹²³,Pineda Eufemio Moreno¹²³,Vitorica-Yrezabal Iñigo J.¹²³,McInnes Eric J. L.¹²³,Winpenny Richard E. P.¹²³

Affiliation:

1. School of Chemistry and Photon Science Institute

2. The University of Manchester

3. Manchester M13 9PL, UK

Abstract

Reaction of oxo-centered Cr(iii) triangles with a lanthanide salt and t-butylphosphonate leads to {Cr₆Ln₂} compounds. Magnetic and EPR studies show the ground state of the individual Cr triangles is S = 3/2 with little communication between them.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01264J

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