Heterometallic 3d–4f {Co2Gd4} phosphonates: new members of the potential magnetic cooler family

Author:

Doroshenko Iaroslav12345ORCID,Buchholz Axel6789ORCID,Domincova Bergerova Eva1011124,Plass Winfried6789ORCID,Pinkas Jiri12345ORCID

Affiliation:

1. Department of Chemistry

2. Masaryk University

3. CZ-61137 Brno

4. Czech Republic

5. CEITEC MU

6. Institut für Anorganische und Analytische Chemie

7. Friedrich-Schiller-Universität Jena

8. 07743 Jena

9. Germany

10. The Centre of Polymer Systems (CPS)

11. Tomas Bata University

12. CZ-760 01 Zlin

Abstract

Three new 3d–4f heterometallic phosphonate complexes with the formula [Na2CoIII2Gd4(L)6(bpy)2(OR)2nSolv (L = SAA3−(1), BSAA3−(2), and NAA3−(3); bpy = 2,2′-bipyridine; OR = OH and OMe; Solv = H2O and MeOH) were isolated and studied in detail.

Funder

Ministerstvo Školství, Mládeže a Tělovýchovy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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