Ligand control of low-frequency electron paramagnetic resonance linewidth in Cr(iii) complexes

Author:

Campanella Anthony J.1234,Nguyen Manh-Thuong5674,Zhang Jun5674,Ngendahimana Thacien89104ORCID,Antholine William E.1112134,Eaton Gareth R.89104ORCID,Eaton Sandra S.89104ORCID,Glezakou Vassiliki-Alexandra5674,Zadrozny Joseph M.1234ORCID

Affiliation:

1. Department of Chemistry

2. Colorado State University

3. Fort Collins

4. USA

5. Physical Sciences Division

6. Pacific Northwest National Laboratory

7. Richland

8. Department of Chemistry and Biochemistry

9. University of Denver

10. Denver

11. National Biomedical EPR Center

12. Medical College of Wisconsin

13. Milwaukee

Abstract

This study reveals, for the first time, the extent to which ligand design strategies can modulate L-band EPR linewidths for an S > 1/2 metal complex.

Funder

Colorado State University

National Institute of Biomedical Imaging and Bioengineering

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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