Coordination behavior of bidentate bis(carbenes) at alkali metal bis(trimethylsilyl)amides-Reference-Cited by-同舟云学术

Coordination behavior of bidentate bis(carbenes) at alkali metal bis(trimethylsilyl)amides

Published:2017 Issue:28 Volume:46 Page:9058-9067
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Koch Alexander¹²³⁴,Görls Helmar¹²³⁴,Krieck Sven¹²³⁴,Westerhausen Matthias¹²³⁴^ORCID

Affiliation:

1. Friedrich Schiller University Jena

2. Institute of Inorganic and Analytical Chemistry

3. D-07743 Jena

4. Germany

Abstract

Crystallization of LiN(SiMe₃)₂ from 2,2,5,5-tetramethyltetrahydrofuran yields the base-free tetramer. Strong carbenes monomerize the lithium bis(trimethylsilyl)amides, whereas the heavier congeners from carbene-stabilized dimers [AN(SiMe₃)₂]₂ with A = Na, K.

Funder

Verband der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01538K

Reference84 articles.

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3. The role of the bis-trimethylsilylamido ligand, [N{SiMe3}2]−, in main group chemistry. Part 1: Structural chemistry of the s-block elements