Anionic N-heterocyclic carbenes featuring weakly coordinating perfluoroalkylphosphorane moieties-Reference-Cited by-同舟云学术

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Anionic N-heterocyclic carbenes featuring weakly coordinating perfluoroalkylphosphorane moieties

Published:2023 Issue:28 Volume:52 Page:9553-9561
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zapf Ludwig¹,Radius Udo¹^ORCID,Finze Maik¹^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Institute for Sustainable Chemistry & Catalysis with Boron (ICB), Julius-Maximilians Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

Abstract

Novel anionic N-heterocyclic carbenes featuring weakly coordinating (C2F5)3PF2−groups at imidazoline were synthesized. These WCA-NHCs are promising ligands with enhanced donor and acceptor properties compared to neutral NHCs.

Funder

Studienstiftung des Deutschen Volkes

Julius-Maximilians-Universität Würzburg

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01249B

Reference88 articles.

1. An overview of N-heterocyclic carbenes

2. Stable Carbenes

3. N-Heterocyclic Carbenes

4. The Beginnings of N-Heterocyclic Carbenes

5. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Fluoride Abstraction Induced by Tris(pentafluoroethyl)difluorophosphorane: A Convenient Way to Synthesize Cationic N-Heterocyclic Carbene- and Cyclic (Alkyl)(amino)carbene-Ligated Copper Alkyne and Arene Complexes;Inorganic Chemistry;2024-04-19

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