s-Block metal complexes of superbulky (tBu3Si)2N−: a new weakly coordinating anion?-Reference-Cited by-同舟云学术

s-Block metal complexes of superbulky (^tBu₃Si)₂N⁻: a new weakly coordinating anion?

Published:2024 Issue:12 Volume:15 Page:4386-4395
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Knüpfer Christian¹^ORCID,Klerner Lukas¹,Mai Jonathan¹^ORCID,Langer Jens¹^ORCID,Harder Sjoerd¹^ORCID

Affiliation:

1. Inorganic and Organometallic Chemistry, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany

Abstract

The extremely challenging deprotonation of the amine (tBu3Si)2NH led to a range of s-block metal complexes with superbulky (tBu3Si)2N−. Depending on metal and solvent, (tBu3Si)2N− can be classified as a halogen-free weakly coordinating anion.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06896J

Reference72 articles.

1. IUPAC , Compendium of Chemical Terminology , Gold Book , ed. A. D. McNaught and A. Wilkinson , Blackwell Scientific Publications , Oxford , 2nd edn, 1997 , online version (2019-) created by S. J. Chalk. ISBN 0-9678550-9-8, 10.1351/goldbook

2. M.Lappert , A.Protchenko , P.Power and A.Seeber , Metal Amide Chemistry , John Wiley & Sons, Ltd , Chichester , 2009

3. Synthetically Important Alkali-Metal Utility Amides: Lithium, Sodium, and Potassium Hexamethyldisilazides, Diisopropylamides, and Tetramethylpiperidides

4. Case for Lithium Tetramethylpiperidide-Mediated Ortholithiations: Reactivity and Mechanisms

5. A Homologous Series of Regioselectively Tetradeprotonated Group 8 Metallocenes: New Inverse Crown Ring Compounds Synthesized via a Mixed Sodium−Magnesium Tris(diisopropylamide) Synergic Base

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Mechanochemical Synthesis of a Sodium Anion Complex [Na⁺(2,2,2-cryptand)Na^–] and Studies of Its Reactivity: Two-Electron and One-Electron Reductions;Inorganic Chemistry;2024-07-29

2. Synthesis of Superbulky Amide Ligands by Addition of Polar Reagents to Sila–Imine;Chemistry – A European Journal;2024-04-10