Origins of ligand-controlled diastereoselectivity in dirhodium-catalysed direct amination of aliphatic C(sp3)

Origins of ligand-controlled diastereoselectivity in dirhodium-catalysed direct amination of aliphatic C(sp3)–H bonds

Published:2021 Issue:21 Volume:11 Page:6960-6964
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Li Qiannan¹,Liu Wenjing²^ORCID,Dang Yanfeng¹^ORCID

Affiliation:

1. Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China

2. Key Laboratory for Environmental Factors Control of Agro-product Quality Safety, Agro-Environmental Protection Institute, Ministry of Agriculture and Rural Affairs, Tianjin 300191, China

Abstract

DFT studies were used to explore the mechanism of ligand-controlled diastereoselectivity in Rh2-catalysed intramolecular C(sp3)–H aminations, and the stereoselectivities were revealed via distortion/interaction and noncovalent interaction analysis.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY01583D

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