Kinetics of phosphine substitution in CpRu(PPh3)2X (X = Cl, Br, I, N3, and NCO)
Author:
Affiliation:
1. Department of Chemistry and Chemical Biology
2. Northeastern University
3. Boston
4. USA
5. Department of Chemistry
6. Wellesley College
7. Wellesley
Abstract
The kinetics of phosphine substitution in CpRu(PPh3)2X (X = Cl, Br, I, N3, and NCO) is consistent with a dissociative mechanism. The complexes react with chloroform to yield CpRu(PPh3)2Cl by a mechanism that involves phosphine loss.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA02793A
Reference42 articles.
1. Ruthenium in Organic Synthesis, ed. S.-I. Murahashi, Wiley-VCH, 2004
2. Halide Effects in Transition Metal Catalysis
3. CpRuCl(PPh3)2/MeI Catalyst System for the [2+2] Cycloaddition of Norbornenes with Disubstituted Alkynes
4. Ruthenium-Catalyzed Cross-Coupling of 7-Azabenzonorbornadienes with Alkynes. An Entry to 3a,9b-Dihydrobenzo[g]indoles
5. Ruthenium-Catalyzed Coupling of Oxabenzonorbornadienes with Alkynes Bearing a Propargylic Oxygen Atom: Access to Stereodefined Benzonorcaradienes
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