Kinetics of phosphine substitution in CpRu(PPh3)2X (X = Cl, Br, I, N3, and NCO)-Reference-Cited by-同舟云学术

Kinetics of phosphine substitution in CpRu(PPh3)2X (X = Cl, Br, I, N3, and NCO)

Published:2017 Issue:55 Volume:7 Page:34425-34434
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Hill David¹²³⁴,Delaney Connor¹²³⁴,Clark Miles¹²³⁴,Eaton Mathew¹²³⁴,Hassan Bakar¹²³⁴,Hendricks Olivia⁵⁶⁷⁴,Dang Duy Khoi¹²³⁴,Kirss Rein U.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Chemical Biology

2. Northeastern University

3. Boston

4. USA

5. Department of Chemistry

6. Wellesley College

7. Wellesley

Abstract

The kinetics of phosphine substitution in CpRu(PPh₃)₂X (X = Cl, Br, I, N₃, and NCO) is consistent with a dissociative mechanism. The complexes react with chloroform to yield CpRu(PPh₃)₂Cl by a mechanism that involves phosphine loss.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA02793A

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5. Ruthenium-Catalyzed Coupling of Oxabenzonorbornadienes with Alkynes Bearing a Propargylic Oxygen Atom: Access to Stereodefined Benzonorcaradienes

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