The underappreciated influence of ancillary halide on metal–ligand proton tautomerism
Author:
Affiliation:
1. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania, 19104, USA
Abstract
Funder
U.S. Department of Energy
Vagelos Institute for Energy Science and Technology, University of Pennsylvania
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00279E
Reference54 articles.
1. Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides
2. Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases
3. A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s −1 for H 2 Production
4. A Functional [NiFe]-Hydrogenase Model Compound That Undergoes Biologically Relevant Reversible Thiolate Protonation
5. Experimental and DFT Investigations Reveal the Influence of the Outer Coordination Sphere on the Vibrational Spectra of Nickel-Substituted Rubredoxin, a Model Hydrogenase Enzyme
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