A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s −1 for H 2 Production-Reference-Cited by-同舟云学术

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s −1 for H 2 Production

Published:2011-08-12 Issue:6044 Volume:333 Page:863-866
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Helm Monte L.¹²,Stewart Michael P.¹,Bullock R. Morris¹,DuBois M. Rakowski¹,DuBois Daniel L.¹

Affiliation:

1. Center for Molecular Electrocatalysis, Chemical and Materials Sciences Division, Pacific Northwest National Laboratory, Post Office Box 999, K2-57, Richland, WA 99352, USA.

2. Chemistry Department, Fort Lewis College, 1000 Rim Drive, Durango, CO 81301, USA.

Abstract

Precisely shaped basic ligands protect highly reactive protons and electrons to help accelerate catalytic hydrogen formation.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference32 articles.

1. Structure/Function Relationships of [NiFe]- and [FeFe]-Hydrogenases

2. Occurrence, Classification, and Biological Function of Hydrogenases: An Overview

3. Investigating and Exploiting the Electrocatalytic Properties of Hydrogenases

4. Enzymes as Working or Inspirational Electrocatalysts for Fuel Cells and Electrolysis

5. Hydrogen Oxidation and Production Using Nickel-Based Molecular Catalysts with Positioned Proton Relays

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