Mechanism of halide exchange in reactions of CpRu(PPh<sub>3</sub>)<sub>2</sub>Cl with haloalkanes-Reference-Cited by-同舟云学术

Mechanism of halide exchange in reactions of CpRu(PPh₃)₂Cl with haloalkanes

Published:2022 Issue:14 Volume:46 Page:6603-6608
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Rich Benjamin S.¹^ORCID,Bissonnette Noah B.¹,Duran Balsa Alejandra¹^ORCID,Yang Mulan¹^ORCID,Meikle Hope¹,Chintala Nithin¹,Dong Sijia S.¹^ORCID,Kirss Rein U.¹^ORCID

Affiliation:

1. Department of Chemistry and Chemical Biology, Northeastern University, Boston, MA 02115, USA

Abstract

Kinetic measurements of the reaction between CpRu(PPh3)2Cl (1a) and 1-bromobutane reveal a nearly first order dependence on the concentration of haloalkane and a negative entropy of activation, ΔS† < 0.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D1NJ06064C

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4. Atom Transfer Radical Addition Reactions of CCl4, CHCl3, and p-Tosyl Chloride Catalyzed by Cp′Ru(PPh3)(PR3)Cl Complexes

5. New, Highly Efficient Catalyst Precursors for Kharasch Additions − [RuCl(Cp*)(PPh3)2] and [RuCl(Ind)(PPh3)2]

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