Oxidation of phenyl and hydride ligands of bis(pentamethylcyclopentadienyl)hafnium derivatives by nitrous oxide via selective oxygen atom transfer reactions: insights from quantum chemistry calculations-Reference-Cited by-同舟云学术

Oxidation of phenyl and hydride ligands of bis(pentamethylcyclopentadienyl)hafnium derivatives by nitrous oxide via selective oxygen atom transfer reactions: insights from quantum chemistry calculations

Published:2016 Issue:3 Volume:45 Page:1152-1159
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Xie Hujun¹²³⁴,Liu Chengcheng¹²³⁴,Yuan Ying¹²³⁴,Zhou Tao¹²³⁴,Fan Ting⁵⁶⁷⁸⁹,Lei Qunfang¹⁰¹¹¹²⁴,Fang Wenjun¹⁰¹¹¹²⁴

Affiliation:

1. Department of Applied Chemistry

2. Zhejiang Gongshang University

3. Hangzhou 310018

4. People's Republic of China

5. Division of Theoretical Chemistry and Biology

6. School of Biotechnology

7. KTH Royal Institute of Technology

8. SE-10044 Stockholm

9. Sweden

10. Department of Chemistry

11. Zhejiang University

12. Hangzhou 310027

Abstract

Frontier molecular orbital theory analysis indicates that N₂O is activated by nucleophilic attack by the phenyl or hydride ligand.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03264D

Reference126 articles.

1. Physical properties and mechanisms of formation of nitrous oxide

2. Depletion of the Ozone Layer in the 21st Century

3. Nitrous Oxide: No Laughing Matter

4. Nitrous Oxide (N 2 O): The Dominant Ozone-Depleting Substance Emitted in the 21st Century

5. Modern chemistry of nitrous oxide

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