A substrate-dependent mechanism for the reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds: insights from quantum chemical calculations-Reference-Cited by-同舟云学术

A substrate-dependent mechanism for the reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds: insights from quantum chemical calculations

Published:2017 Issue:1 Volume:41 Page:198-203
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kuang Jian¹²³⁴,Li Yang¹²³⁴,Wang Lihong¹²³⁴,Wu Zunyi¹²³⁴,Lei Qunfang⁵⁶⁷⁴,Fang Wenjun⁵⁶⁷⁴,Xie Hujun¹²³⁴

Affiliation:

1. Department of Applied Chemistry

2. Zhejiang Gongshang University

3. Hangzhou 310018

4. People's Republic of China

5. Department of Chemistry

6. Zhejiang University

7. Hangzhou 310027

Abstract

The reactivity difference between ketones and aldehydes towards the ruthenium silylene hydride complex is dependent on the substituents of the carbonyl substrates.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C6NJ02361D

Reference40 articles.

1. Redistribution of Methyl Groups between Silicon Centers in Bis(silyl)tungsten Complexes: Silyl Silylene Complex Intermediates as the Source of Interligand Reactivity

2. Activation of the Si-Si Bond by Transition Metal Complexes

3. Stoichiometric and Catalytic Behavior of Cationic Silyl and Silylene Complexes

4. Reactivity of silylene complexes

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Ruthenium and Osmium Complexes Containing NHC and π-Acid Ligands;Comprehensive Organometallic Chemistry IV;2022