Non-innocent PNN ligand is important for CO oxidation by N2O catalyzed by a (PNN)Ru–H pincer complex: insights from DFT calculations-Reference-Cited by-同舟云学术

Non-innocent PNN ligand is important for CO oxidation by N2O catalyzed by a (PNN)Ru–H pincer complex: insights from DFT calculations

Published:2018 Issue:43 Volume:47 Page:15324-15330
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Xie Hujun¹²³⁴^ORCID,Zhang Yutong¹²³⁴,Xiang Chuyue¹²³⁴,Li Yang¹²³⁴,Fan Ting⁵⁶⁷⁴,Lei Qunfang⁸⁹¹⁰⁴,Fang Wenjun⁸⁹¹⁰⁴^ORCID

Affiliation:

1. Department of Applied Chemistry

2. Zhejiang Gongshang University

3. Hangzhou 310018

4. P. R. China

5. School of Chemistry and Chemical Engineering

6. South China University of Technology

7. Guangzhou 510641

8. Department of Chemistry

9. Zhejiang University

10. Hangzhou 310027

Abstract

It was found that the catalytic cycle for CO oxidation by N₂O proceeds in three stages: N₂O activation to form a (PNN)Ru–OH intermediate, CO insertion into the Ru–OH bond to form a (PNN)Ru–COOH intermediate and CO₂ release from (PNN)Ru–COOH.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03304H

Reference74 articles.

1. Physical properties and mechanisms of formation of nitrous oxide

2. Depletion of the Ozone Layer in the 21st Century