Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion-Reference-Cited by-同舟云学术

Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion

Published:2024 Issue:10 Volume:11 Page:2829-2833
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Malakhova Ekaterina V.¹²,Kostromitin Vladislav S.¹³,Levin Vitalij V.¹^ORCID,Dilman Alexander D.¹^ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation

2. Higher Chemical College, D. Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow, Russian Federation

3. Lomonosov Moscow State University, Department of Chemistry, Leninskie Gory 1-3, 119991 Moscow, Russian Federation

Abstract

Commodity chemicals are used as alkylating and reducing agents for radical addition to alkenes. The method is based on activation of the strong C–Cl bond by the radical anion of carbon dioxide.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00228H

Reference41 articles.

1. Carbon–carbon bond formation and green chemistry: one dream and 30 years hence

2. Generation of Alkyl Radicals: From the Tyranny of Tin to the Photon Democracy

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5. Recent Advances in Photoredox‐Mediated Radical Conjugate Addition Reactions: An Expanding Toolkit for the Giese Reaction

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